Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2 N′,O 2}tin(IV)
نویسندگان
چکیده
The five-coordinate Sn(IV) atoms in the two crystallographically independent mol-ecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N'-[1-(5-chloro-2-oxidophen-yl)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazide, displays inter-molecular O-H⋯N hydrogen bonding, which stabilizes the overall compound.
منابع مشابه
{N′-[1-(5-Bromo-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2 N′,O}dibutyltin(IV)
The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination. Both butyl chains and the naphth-yl-oxy portion are disordered over two sets of sites of equal occupancy.
متن کاملDicyclohexyl{3-hydroxy-N′-[1-(2-oxidophenyl-κO)ethylidene]-2-naphthohydrazidato-κ2 N′,O}tin(IV)
In the title compound, [Sn(C(6)H(11))(2)(C(19)H(14)N(2)O(3))], the Sn(IV) atom is O,N,O' chelated by the deprotonated Schiff base ligand and exists in a cis-trigonal-bipyramidal environment, completed by the two cyclohexyl ligands.
متن کامل(3-Hydroxy-2-{[1-(2-oxidophenyl)ethylidene]amino-κ2 O,N}propanoato-κO 1)diphenyltin(IV)
In the title compound, [Sn(C(6)H(5))(2)(C(11)H(11)NO(4))], the tin(IV) atom is penta-coordinated in a distorted trigonal-bipyramidal SnC(2)NO(2) geometry. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers. Weak C-H⋯O inter-actions further link the dimers into chains extending in [010].
متن کاملDi-n-butyl[4-hydroxy-N′-(3-methoxy-2-oxidobenzylidene-κO 2)benzohydrazidato-κ2 N,O]tin(IV)
In the title compound, [Sn(C4H9)2(C15H12N2O4)], the Sn(IV) atom is coordinated by the N, O and O' atoms from the tridentate Schiff base dianion in an overall cis-C2SnNO2 trigonal-bipyramidal geometry. Adjacent mol-ecules are linked by O-H⋯O hydrogen bonds, forming a chain running along [001].
متن کامل(1H-Imidazole-κN 3){N-[1-(2-oxidophenyl-κO)ethylidene]-l-phenylalaninato-κ2 N,O}copper(II)
In the title compound, [Cu(C(17)H(15)NO(3))(C(3)H(4)N(2))], the Cu(II) atom is four-coordinated by two O atoms and the N atom of the tridentate Schiff base ligand, and one N atom from the imidazole ligand in a distorted square-planar geometry. In the crystal structure, mol-ecules are linked into dimers by inter-molecular N-H⋯O hydrogen bonds.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010